Probably more than you want to know but I will put it out there.
Batteries in series increase your voltage (faster or more kV).
Batteries in parallel increase your capacity (runtime and amps).
Each battery has a configuration for the pack, like "4S1P". Which means 4 cells in series and 1 cell parallel. Thus 4x3.7=14.4V.
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If you have a 6S or 8S setup it's usually two 3S or two 4S (respectively) in series. Add up the "S"s.
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The only time I've seen people run parallel is for high current requirements like speed running or drag racing. Then you add up the mAH.
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If you want to be fancy you can do both. It gives you more S (volts) and more mAH (runtime and current) but it's heavy, bulky and very expensive. So unless you have a specific application it's probably not for you. Oh and it's a lot of wires, so don't mess it up, because more S mean bigger fires.
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