A lipo charger will not discharge a lipo down past unsafe voltages. At least not a modern one, anyway. I use a SkyRC lipo discharger to take them down to about 3v/c, and then I take them outside and put them in an ammo can, where I plug a 5v fan and an LED in to the pack. This will drain a 2S pack down to about 2–2.5v. When the LED is no longer being lit at all, I then strip the wires and twist them together and leave them there for a week. That will drop the 2S pack voltage down to about .1 - .2V. At that point, you can throw it in the trash. Technically, at 2.5V there's not enough energy left in the pack to be reactive even if you drive a nail through it, but I like to take it down all the way.
*NOTE* If you're using bigger lipos like 4S or 6S you'll have to use a 9v or 12v fan until it won't run anymore, and then you can switch to the 5V fan and LED.
The other thing you can do, if that's too much hassle for ya, is to cut the connector off of the battery, cut the wire to different lengths so you can strip the ends of both the wires, but they can't touch and place it in a jug of salt water and leave it there for a couple of weeks. That will also discharge the lipo pretty good. I find this method messy and I have all the other fans and LEDs etc. lying around my hobby room, so I opt for my method, even though it's a little more involved.