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Cells

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That is merely the number of individual batteries that make up the power supply. 7-cell has 7 batteries. 6-cell has 6. Typically adding more cells increases the voltage of the pack.
 
Candyman is correct. Each cell is 1.2 volts. Multiply the total of cells by that voltage, to get the voltage going to the motor. More voltage, more RPMs.
 
More voltage also means more wear on the motor. Be carefully, certain motors can only handle a certain amount of cells. As a general rule, 540 (also called 05 motors, or standard car motors) really should only be run on 7 cells or less. They can be run on 8, but they won't last long at all. On 7 cells they'll wear a lot faster than on 6 and need to be rebuilt more often.
 
And, 7 cells will get less run time then an equal quality 6 cell pack. Anytime extra voltage is pushed to a motor it will create more heat, heat equals resistance.
 
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