adding shims has several different effects on a nitro engine. mainly it would relate to nitro percentage and ignition timing.
When upping the nitro percentage two things change. first off is the fuel to air ratio. higher % nitro has a quicker flash, and in order to compensate this quicker flash a richer air/fuel ratio is required. so now that more fuel is entering the combustion chamber it becomes more difficult to compress. hence the need fot additional room atop the piston!
second reason and equally important. ntro engines are like diesel engines in sence that it ignights fuel in relation to compression. if compressed to soon it fires too soon.
so if your engine is running hot and tempermental, than yes by adding a thicker head shim may tone it down and give you a richer more ideal mixture.